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Reaction with chlorates, perchlorates, Cl0, Gastrointestinal system effects by inhalation. Or treating antimony trichloride solution with sodium thiosulfate.Īlternatively, heating antimony metal or antimony trioxide with sulfur forms antimony trisulfide:2 Sb + 3 S → Sb 2S 3Īll these above preparative methods yield amorphous antimony trisulfide. It is also prepared by passing hydrogen sulfide into a solution of antimony trichloride: The pure molten material is collected and cooled. The ore is then heated to 550-600☌ in a perforated vessel. Stibnite is separated from other ores by grinding and flotation.
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The pure sulphide is obtained from its ore. It is used as catalyst, additive, anti- blushing agent, heat stabilizer and used in the production of ruby-colored glass and in plastics as a flame retardant. UsesĪntimony(III) sulfide is used as a red dye in rubber vulcanization. In pyrotechnics, Bengal fires manufacture of ruby glass, matches, explosives as a pigment in paints. It is also used to make percussion caps that set off explosives. UsesĪntimony trisulfide is better known as the mineral stibniteĪnd is used as a yellow paint pigment and in the manufacture of ruby glass, fireworks, and It is used in fireworks in certain types of safety matches as a pigment in paints and in the manufacture of ruby glass.
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OccurrenceĪntimony trisulfide occurs in nature primarily as the mineral, stibnite, which consists of two parallel Sb4S6 chains linked together.
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Natural stibnite is black orthorhombic crystal or grayish-black powder the compound also exists as an amorphous substance in yellow-red modification distorted octahedral arrangement density 4.64 g/cm 3 for the natural stibnite and 4.12 g/cm 3 for the red modification melts at 550☌ vaporizes around 1150☌ insoluble in water (1.75mg/L at 18☌) and acetic acid soluble in hydrochloric acid and caustic soda solution also, soluble in alcohol, ammonium hydrosulfide and potassium sulfide.